The TOWIE star was totally sensational in a floor sweeping scarlet gown cinched at the waist with a metallic belt.
Danielle, 28, walked the red carpet solo at the Dorchester Hotel on Park Lane, London, after hinting last month at a split from TOWIE co-star boyfriend James 'Lockie' Lock.
She shared a cryptic quote to social media that read: "She loved him and he loved her but it wasn't that simple."
"Lots of people have been asking what's been going on with me and James..." she added. "I really don't want to go into it but feel like I have to as I'm getting asked constantly. This quote pretty much sums us up I'm afraid and I just want to move on in my life now."
What's the betting she doesn't stay single for long, though?
Danielle admitted before arriving at the glitzy ceremony that she hadn't quite figured out what to wear, tweeting: "Why do I always leave everything to the last minute dress finally sorted for tonight @TVChoice awards."
Although she went sans plus one, Danielle had plenty of people to hang about with as half the TOWIE cast seemed to be in attendance! Megan McKenna, Pete Wicks, Chloe Sims, Chloe Lewis, Chloe Meadows and Courtney Green were among the stars spotted on the red carpet.
The Only Way Is Essex was nominated in the 'Best Reality Show' category, up against Bear Grylls: Mission Survive, Celebrity Big Brother and I'm A Celebrity… Get Me Out Of Here. It was I'm A Celeb that scooped the prize.
10 reasons why we want to be in TOWIE: