Adele At The BBC will see the music superstar perform classic tracks as well as songs from her highly-anticipated new album 25 with a live band.
Hosted by Graham Norton, the hour-long special will also see Adele talk about her career and life to date.
The world-exclusive show will mark Adele's first television performance since she performed 'Skyfall' at the 85th Academy Awards in February 2013.
"I can't wait for the show," said Adele. "The BBC has been wonderful to me over the years and Graham and I get on great so it's going to be a laugh."
In what's being dubbed as an "unmissable night of music", Graham added: "This is the music event of the year and I'm thrilled to be part of bringing it to BBC One. This opportunity to spend an hour with Adele, her music and her stories is a truly rare treat. If I wasn't hosting this special I'd be sat at home watching it!"
Adele At The BBC will be recorded in London on Monday 2 November.
Last week, Adele premiered her new single 'Hello', some three years after 'Skyfall'. As well as sending social media into a frenzy with her return, and the internet coming up with hilarious memes and mash-ups of her and Lionel Richie, Adele has also now broken the Vevo record for the most video views in 24 hours.
Adele's third studio album, 25, is due for release on 20 November.
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