According to The Sun, the 54-year-old will follow in his brother Stephen Baldwin's footsteps and join the new series of the reality show, which kicks off this month.
Daniel is the second eldest of the Baldwin brothers, behind 30 Rock star Alec Baldwin. Stephen appeared in the seventh series of CBB in 2010.
The new series of the Channel 5 reality show is set to return on Thursday 27 August and housemates will be met with a UK Vs. USA theme.
In a new twist for Big Brother, housemates will be pitted against each other and they'll feel far from home as plenty of surprises will be in store.
The new series will see "epic" tasks and lots of challenges and twists, which is sure to create lots of drama.
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