Natalie, who plays Alicia Metcalfe, arrived with her husband James Shepherd for X Factor star Carolynne Poole's album showcase on Thursday evening (28 May).
The couple were joined at the event by Corrie's Catherine Tyldesley and Alan Halsall.
Natalie walked down the red carpet in a black playsuit and heels, and was all smiles despite revealing her "very sad" news last week.
Natalie confirmed that she will be bowing out of the soap as Alicia after five years.
Speaking about her exit, she said: "I've had the most incredible five years at Emmerdale and made some wonderful friends. I'm so grateful to the writers, directors, producers and everyone I've worked with.
"This year has been such a highlight and so amazing that I felt now was the right time to say bye to Alicia and see what the future holds."
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