The 'FourFiveSeconds' took to the stage in an emerald green jacket, a cleavage-baring skintight black dress and thigh-high patent boots.
She finished off her look with round-rimmed sunglasses and a chocker, which read, 'Versace'.
Rihanna's performance was pretty spectacular, as she arrived in a helicopter. Well, that's one way to make an entrance!
The awards ceremony marked the first time Rihanna performed her brand new single, 'B***h Better Have My Money'. RiRi, 27, unveiled the track last week as the second official song from her upcoming new album.
She also released the artwork cover, showing her posing braless in a leather jacket while sporting some flamboyant drop earrings and rocking some serious eyebrows.
Speaking about her new music earlier this month, Rihanna said: "I wanted songs that I could perform in 15 years; I wanted an album that I could perform in 15 years. Not any songs that were burnt out.
"I find that when I get on stage now, I don't want to perform a lot of my songs. They don't feel like me. So I want to make songs that are timeless."
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