Following her appearance on Lorraine, the 25-year-old was in high spirits and flashed a big smile as she headed home.
Looking oh-so-gorgeous, Rochelle braved the cold to flash her pins in a flirty skirt and we're absolutely loving her outfit choice!
Proving she's the perfect advert for her own designs, the starlet worked the black and white striped lantern skirt from her new Very collection - teaming it with a low cut jumper and stylish leather jacket on top.
To finish her look, Rochelle wore a cute gold pendant around her neck. Letting her chestnut brown locks fall past her shoulders, the mum-of-one sported lashings of mascara and plenty of gloss on her lips.
Rochelle has had a week's worth of wardrobe winners, stunning on the red carpet in her bespoke fishtail gown at this year's National Television Awards.
Attending on the arm of husband Marvin Humes, Rochelle and her other half looked like the perfect pair at the bash - although she did reveal to Lorraine Kelly her dress caused a few problems between them.
She said: "I was lucky enough to have my dream dress made for me. But, I couldn't move. I couldn't sit down. Marvin was not happy with the dress because he kept standing on it. He kept getting into trouble... It was lovely, though."
It definitely was!
Meanwhile, Rochelle also spoke about her support for this year's Comic Relief.
Having been involved with the charity event in the past, the singer praised Comic Relief for its work and told Lorraine about how she has been raising awareness this time round.
As part of its 'Funny with Money' campaign, Rochelle bravely let Marvin take to her glam kit and put on her war paint for her.
Getting to work, it seems the Capital FM DJ got his hands on every brush and product in his wife's make-up bag to create her new look.
"He had an absolute ball," Rochelle revealed. "And I knew why when I looked in the mirror! [Marvin] said he was going for the 'more is more' look."
We can tell!!
Comic Relief's Red Nose Day is back for 2015 on BBC on 13 March.
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