Ed was joined on the front row by Tinie Tempah and Pixie Lott's model boyfriend Oliver Cheshire, as well as Ellie Goulding, Liam Payne and his girlfriend Sophia Smith.
Ed, who played Chuck Bass in US drama series Gossip Girl, looked handsome in a grey suit as he posed for pictures on the plush pink carpet before taking his seat in the prime spot.
Commenting on a photo of himself sitting on the front row, the 27-year-old said: "What a beautiful view at the #VSFashionShow."
Ed watched a host of supermodels, including Alessandra Ambrosio and Lily Aldridge, walk the most famous catwalk on earth.
The glitzy affair featured stunning Victoria's Secret Angels strutting their stuff in lace lingerie, towering embellished heels and extravagant super-sized wings.
Captioning another photo of himself, Tinie and Oliver, Ed said: "Good ol' lads enjoying the #VSFashionShow."
Earlier this week, Ed made a cheeky request via Twitter to attend the high-profile catwalk show.
Ed publicly asked for tickets after hearing the already sold-out extravaganza was being filmed in London for the first time.
And just three hours later, his wish came true, as the show's executive producer Ed Razek said he would send a ticket Ed's way. Lucky boy!
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Victoria's Secret 2014 catwalk:
Copyright: WENN Lia Toby