Rita was appearing on the late-night American sketch show to perform her latest single 'Black Widow' with Iggy Azaela, but backstage the 23-year-old couldn't resist grabbing a selfie with the legendary Bruce Almighty star.
Well, who can blame her?!
Jim had returned to Saturday Night Live as a celebrity host after first fronting the show back in 1996 and, clearly wanting to mark the occasion, Rita made sure to grab a cheeky snap with the actor.
Cuddling up to Jim, Rita looked a little more than excited to be posing for a photo with the famous comedian. Aptly pulling a silly face, a glamorous-looking Rita pointed towards the camera while Jim grinned happily next to her.
Captioning her photo, the singer said: "SNL tonight! Surprise thank you @thenewclassic and SNL! Black widow with the squad."
Rita's promo trip Stateside comes after she recently announced she would be joining the judging panel for The Voice UK.
Taking a seat on the fourth and final red chair, Rita will join returning judges Ricky Wilson, Tom Jones and will.i.am for the next season of the show, set to air next year.
Earlier this month, Rita had her first taste of being a judge on the show as first auditions got underway.
Speaking about her new role, the starlet said: "So excited to be part of - and for my team to win - The Voice this series! Let's have some fun will.i.am, Tom and Ricky! I'm really looking forward to the blind auditions – and spinning in my big red chair. EXCITED!!!!"
We can't wait to see her in action!
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