The long-time couple surprised fans by marrying in secret on Saturday, 23 August at their Chateau Miraval in France.
Angelina and Brad's wedding pictures appear in the new issue of People magazine, which boasts a stunning photo of Angelina in her ivory silk wedding dress, complete with a unique veil featuring drawings designed by her and Brad's six children.
All the kids had major parts to play in the private reception, which was reportedly attended by just Brad's parents, siblings and their own children.
Angelina was walked down the aisle by sons Maddox, 13, and Pax, ten while daughters Zahara, nine, and Vivienne, six, threw rose petals. Daughter Shiloh, eight, and son Knox, six, acted as ring bearers.
The non-denominational ceremony was officiated by a California judge. Angelina and Brad had obtained their wedding licence in California before flying to France for the ceremony.
Brad proposed to Angelina in 2012, following an eight-year relationship. They initially met on the set of romantic action movie Mr and Mrs Smith, where they played a married couple.
This issue of People is available on newsstands from Wednesday.