Keeping Up With The Kardashians star Kim arrived at the awards ceremony in Los Angeles on Sunday 10 August.
Kim, who is married to rapper Kanye West, kept all eyes on her in the Balmain midriff-baring leather crop top and high-waisted skirt, which she teamed with Balenciaga heels.
The 33-year-old parted her sleek black locks in the middle and stunned as she posed for photographers.
Looking ever so glam and sultry, Kim rocked smoky eye make-up, contoured cheeks and a nude lip.
Mum-of-one Kim was joined by her younger sisters Kendall and birthday girl Kylie Jenner.
The family were successful on the night after Keeping Up With The Kardashians was crowned best 'Reality TV Show', and so the sisters gathered on stage to collect their surfboard trophies!
Along with her sisters, Kim was also nominated for 'Choice Reality Personality: Female', but they lost out to singer and The Voice US judge Shakira.
Taking to Twitter after their win, a happy Kim said: "We won!!!! Thank you to everyone who voted for us for best Reality Show!!!! #Surfboard."
After the ceremony, Kim, Kylie and Jenner headed to Nobu Malibu, to celebrate Kylie's 17th birthday.
Elsewhere, this week it was reported that Kim, along with her sisters Kourtney and Khloe, are set to release their very own haircare range.
What do you think of Kim's bold outfit? Tell us below, as the best comment from across the website each week wins £50!
Reveal is now on Google Plus! Join us here for the latest pictures, fashion and celebrity news!