Grabbing the opportunity to get snap happy with Enrique, Myleene and her fellow Loose Women panellist, Andrea McLean, posed alongside the good-looking singer as they stopped for a post-interview selfie.
And ladies' man Enrique was more than happy to oblige!
Viewers watched Myleene and Andrea interview the Spanish singer in a special one-on-one during yesterday's Loose Women (10 July).
Entertaining her audience, Myleene, 36, revealed she has been learning how to speak Spanish and couldn't wait to flaunt her newly-learnt skills to Enrique.
After a beautiful rendition of 'Head, Shoulders, Knees and Toes' in Enrique's native tongue, the mum-of-two got a little more than she bargained for when she cheekily asked the singer for a quick cuddle.
Clearly impressed with her Spanish lingo, Enrique took her up on her offer, giving Myleene a quick squeeze for her efforts. N'aww.
Unfortunately, not as far ahead as Myleene in her range of vocab, Andrea could only muster up a quick, but very useful, phrase: "Two beers please."
We bet she's digging out her Spanish phrase book now!
Enrique's appearance on the show comes as he promotes his latest album, Sex and Love, which features collaborations from other stars including Kylie Minogue, Pitbull and Flo Rida.
With a great number of albums already behind him (Enrique's new album is his tenth!), the singer insisted that writing new material doesn't always go to plan.
He said: "Sometimes I go nuts, it's one thing that you can't really plan writing songs... You can't plan an album, you can't plan when you're going to write that one song that feels special, that's the thing that can be frustrating... But it is fun too!"
For Enrique, he especially enjoys coming back to tour the UK as it's the one place he always wanted to make a name for himself.
"I love touring the UK... It was always one of those places that I wanted to be successful in musically, the fans here are extremely loyal", he said.
And judging by these pics, the Loose Women girls are more than happy to have him here!
Reveal is now on Google Plus! Join us here for the latest pictures, fashion and celebrity news!