A photo of the couple kissing after exchanging vows was uploaded to Kim's account on 27 May, and has been favourited by fans nearly two million times.
That makes it the most liked photo in Instagram history – and it's only been on her site for a mere three days!
Kim and Kanye married in Florence, Italy on 24 May, tying the knot at the 16th century Fort Belvedere in front of family and celebrity friends.
There had been massive speculation ahead of the nuptials as to what dress Kim would wear and what designer she'd choose, as Kim (uncharacteristically) kept the details private.
Perhaps that added to the huge interest in the first photo?
Kim, 33, wore a beautiful Givenchy Haute Couture white lace gown to marry Kanye, who opted for a custom-made Givenchy tux.
Their wedding in Florence came following a week of pre-nuptial celebrations in Paris, France, which included a private reception at the Palace of Versailles where Lana Del Rey performed for guests.
Kim then used Instagram and Twitter to announce she'd changed her name to Kim Kardashian West.
Since the lavish wedding, the newlyweds have been keeping a surprisingly low profile.
They jetted to Cork, Ireland to begin their honeymoon. While there, they visited other beauty spots and counties in the country, as well as enjoying low-key cinema visits.
Yesterday, they left Ireland for the Czech Republic, jetting into Prague where it's expected they'll combine the next leg of their honeymoon with attending the wedding of Kanye's stylist.
New Season of Keeping up with the Kardashians launches Sunday 15th June @ 9pm on E! For more pictures from Kim and Kanye's wedding visit the E! website.
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Couples who married in 2014 in pictures:
Copyright: WENN Twitter @realbkbrown / Instagram @norman cook / E! Instagram @kimkardashian / Rex Features