The Essex favourites joined the superhero movie's stars Andrew Garfield, Emma Stone and Samuel L. Jackson at the world premiere in London's Leicester Square on Thursday (10 April).
Ricky was as dapper as always in a smart suit, while Jessica looked ready for summer in a fun and flirty floral bralet and matching pencil skirt.
Love her look? Then very good news! You can get Jess' exact outfit from New Look without breaking the bank. The skirt retails for £14.99 and the bralet for £12.99.
Our favourite part of her outfit, however, was that pretty amazing lemon slice clutch.
TOWIE's eleventh series came to an end earlier this month with Jessica and Ricky hosting a prince and princess-themed finale party for their family and friends.
Next up for Jessica is something slightly different – leading the judging panel for a talent contest in North Wales called The Only Way Is Wrexham.
"Wales is of course famous for its many singers and I can't wait to hear the very best new voices taking part in this show," she said.
"However, it isn't all about singing, as judges we want to see amazing dancers, really funny and creative comedians, speciality acts, magicians or entertainers with any other talent. So long as it's fresh and something new, we want to see it."
Jessica is a singer herself, charting with her track 'Dance All Night' in 2012.
She recently told Reveal: "I've still got my record deal and we're probably going to be working on material later this year, and hopefully it might get somewhere. It's taking a while for people to actually care because I'm on TOWIE. When you're on a reality show, if you want to go into the music industry it's a really long, hard road, which I completely understand."
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