The duo feature on Spanish track 'Adrenalina' by Puerto Rican rapper Wisin and, in its accompanying music video, things heat up between the two pop stars.
Jennifer, 44, looks fierce and steals the spotlight in the visual, showing off her killer body in a black all-in-one bodysuit while breaking out into raunchy dance routines.
Meanwhile, 'Livin' La Vida Loca' hitmaker Ricky stays close by Jennifer's side and grabs hold of her waist as she strokes his face. He even nibbles on Jennifer's ear!
The uptempo track sees the two stars unleash their provocative side and we bet Ricky was loving every minute of it! (watch the video below).
Jennifer has been keeping very busy recently and last month, the mum-of-two headed to Fort Lauderdale with rap star Pitbull to shoot the visual for their new collaboration.
Alongside Brazilian singer Claudia Leitte, Jennifer and Pitbull have recorded 'We Are One (Ole, Ola)' as FIFA's official song of the 2014 World Cup.
'On the Floor' singer Jennifer, who is currently a judge on American Idol, also recently unveiled new songs 'Same Girl' and 'Girls' which will be taken from her new studio album, due out later this year.
Jennifer, who is dating dancer Casper Smart, has collaborated with the likes of Chris Brown, Robin Thicke and Big Sean for the album.
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Watch Jennifer and Ricky get steamy in the 'Adrenalina' video below: