The 25-year-old wore a black frock for the occasion, which featured a daring thigh-high split and a long train that got caught under her heel on the red carpet - oops!
Although she was pictured unhooking the bottom of her dress from her shoe in front of everyone, Daisy didn't seem embarrassed in the slightest and shrugged off any awkwardness by continuing to pose for the cameras.
What a pro!
In fact, despite the fashion blunder Daisy still loved her outfit from last night (19 February), referring to it as "the gothic ethereal dream dress" this morning.
One person who no doubt appreciated the sexy frock too was Brit Award winner Sam Smith, who accompanied Daisy to the ceremony and partied with her afterwards.
Sam won the Critics Choice award on the evening and seemed to be celebrating in style with the brunette beauty on his arm.
He also met up with family member and fellow artist Lily Allen, who rocked a faux yellow ponytail for the ceremony.
Daisy posted a photo of the twosome on her Instagram and also confirmed that Sam was her "date" for the night.
She wrote: "My date @samsmithworld and his fit cousin @lilyallen."
After watching the awards being dished out at London's O2 Arena, Daisy and Sam headed to a record label party and were seen hugging and kissing, according to the Mail Online.
This isn't the first fit female to hang out with Sam this month, as he also met Taylor Swift at her gig in the capital.
Taylor later admitted that she was a big fan of the UK singer's music.
What do you think of Daisy's dress? Let us know, as the best comment from across the website each week wins £50!
Check out other looks from the Brits below.
Copyright: WENN Lia Toby
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