Fearne and Dermot were hosting live from the red carpet for E! but, once their work was done, the pair were able to let their hair down and have some fun.
The pals headed backstage at the glamorous event and took full advantage of a selfie photo booth that had been set up for the celebrity guests.
Heading in together, Fearne - who was glammed up in a gold sequinned dress - pulled a somewhat startled expression and held her fingers in a peace sign, while grasping her clutch bag with her other hand.
Dermot, meanwhile, is turning towards his E! co-star with a bemused look on his face while holding onto a leather wallet.
Prior to the event, held at the Royal Opera House, he had tweeted: "Hi ho hi ho it's off to the @BAFTA s I go with Ferney C @Fearnecotton we're live on @EOnlineUK hi ho' #prettybadiknow."
Check out the full BAFTA winners list here!
BAFTA 2014 red carpet gallery:
Copyright: WENN Lia Toby