The US reality star, 32, tweeted the photograph as part of Twitter's 'throwback Thursday' trend, telling fans that it was taken backstage during a past calendar shoot.
Kim, who is now mum to baby daughter North, is sat texting on her mobile while seriously flashing the flesh as stylists get to work on her make-up.
She is topless underneath a tiny leather jacket and is wearing just a pair of bondage-style pants and thigh-high boots on her bottom half. Kinky!
Posting the risqué snap on the social networking site, Kim commented: "#tbt calendar glam."
These days, although she's a fan of wearing seriously tight clothes, Kim tends to cover up her curvaceous figure with dresses.
Although, there was that white swimsuit picture which showed off Kim's post-baby body - and famous bottom - in October.
In July, Kim gave birth to her first child North and she is now engaged to rapper Kanye West. Perhaps her leather bondage days are now behind her?