Dressed to impress, Paris wore a stunning white lace gown for the highly anticipated ceremony, which was held at the Staples Centre in Los Angeles on Sunday (26 January), and she tied her blonde locks up into a chic 'do with plenty of volume at the crown.
Meanwhile, UK chart-topper Ed ditched his trademark hoodies for a smart suit with a red tie.
However, he did manage to incorporate some of his comfy fashion sense into the outfit by donning a pair of black trainers with his dapper trousers and jacket.
Paris, 32, bumped into Ed, 22, backstage at the prestigious award show and proved what a big fan of the pop star she is by requesting a photo and posting it straight to Instagram.
She captioned the snap: "Great meeting @TeddysPhotos last night backstage at The Grammys. Such a nice guy, love his song "The A Team" Such a beautiful song."
Ed has gained a huge following in America and his Stateside fan base was particularly strong last year, as he joined Taylor Swift on her US tour.
But although he has a great deal of celebrity supporters now and famous females asking for pictures, it sounds like Ed was excited to meet two singers a bit closer to home.
This week the 'Lego House' star met up with Irish duo Jedward and tweeted: "Hanging out with JEDWARD now. Jepic".
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