The Westlife singer jetted back to the UK on Wednesday morning (11 December) following his three-week stint in the Australian jungle, but rather than heading home for some well deserved rest, he slipped on a dapper suit to attend the charity night.
Kian missed last night's I'm A Celebrity... Coming Out show to present an award alongside Holly Willoughby at the glitzy show, although he couldn't fully escape IAC for the night as his glamorous campmate Amy Willerton was also in attendance.
'Flying Without Wings' star Kian was without actress wife Jodi Albert, who had flown to Australia to greet him after his King of the Jungle victory, as she stayed at home with their young son Koa.
"I'm missing my number 1 lady @JodiAlbert on my arm also. Don't like been away from her and Koa already. Be home soon family," he tweeted.
Kian was reunited with adorable Koa yesterday after a month away from home as the youngster did not travel with Jodi to Australia to visit his dad.
Meanwhile, while here at Reveal.co.uk we think Kian looked very handsome on the red carpet last night (wearing what he said was the only suit that now fits him following his jungle weight loss), he admitted to fans he didn't have the most suave starts to his glam night.
"As I'm walking out the door my suit jacket got caught on the door and ripped!" he tweeted.