The Wanted actress, 38, attended the 2013 Governors Awards in Hollywood last night (16 November) and looked seriously stunning in a black embellished floor-length gown.
Showing absolutely no signs of the double mastectomy she underwent earlier this year, the mother of six smiled at waiting photographers as she arrived at the glamorous ceremony, hosted by the American Academy of Motion Picture Arts and Sciences (AMPAS).
Joined by clean-shaven Brad and their eldest son, Cambodian-born Maddox, 12, the trio could definitely have won the award for best looking family!
Instead, the Hollywood film industry honoured Angelina with the Jean Hersholt Humanitarian Award for her work with refugees and for advocating human rights throughout her film career.
Filmmaker George Lucas presented Angelina with a golden Oscar statuette, after which she "thanked everyone from the heart".
She went on to thank Brad, fighting back tears to say: "My love. Your support and your guidance make everything I do possible."
Aimed at her son, she said: "I'm not going to cry, I promise. I'm not going to embarrass you.
"You and your brothers and sisters are my happiness and there is no greater honour in this world than being your mum," she said, paying tribute to the couple's other children, Pax, nine, Zahara, eight, Shiloh, seven, and five-year-old twins, Knox and Vivienne.
Earlier this week, Disney fans were given a first glimpse of Angelina as Mistress Of All Evil in a newly-released trailer for the upcoming film Maleficent, which is set to hit cinemas in 2014.
Her youngest daughter Vivienne stars as a young Aurora.
What do you think of Angelina's award outfit? Tell us what you think below!
Watch the official trailer for Maleficent: