The reality star made a fashion statement in the jazzy pair of specs as he walked down the blue carpet at the Odeon in London's Leicester Square.
Joey, who looked rather tanned, coordinated his outfit wearing a chunky gold watch with skinny jeans, a white t-shirt, trainers and a beige cardigan.
Newly-single Joey arrived alone and without a girl on his arm, but he was all smiles as he gave his signature pose to fans and photographers.
The 21-year-old earlier teased on Twitter that he was using products from his own beauty line to get spruced up for the big event.
He tweeted: "Putting some of my JOEY ESSEX Beach Spray and Putty on... Mixing it together to create my D'REEM look for 'We're The Millers' Premiere!"
Once Joey got inside, he also got a view of leading lady Jennifer Aniston who stood alongside her cast to give an opening talk before the start of the film.
Joey is clearly a fan of the popular Hollywood actress, as he commented on a photo of her, simply saying his trademark phrase "reem".
The Fusey shop owner seemed pretty impressed with the film too. Taking to Twitter after the screening, he told his fans: "The film premiere tonight was one of the best films!!! Loved it!!!"
We're The Millers hits cinemas on 23 August.
Watch a trailer for We're The Millers below: