The blonde wowed on the red carpet in a black leotard and a flowing emerald green maxi skirt at the Odeon in London's Leicester Square.
Kimberley was obviously giving MIC star Lucy Watson a run for her money, who showed off some leg action of her own at the same premiere.
Kimberley finished off her look with some strappy sandals and kept her hair loose and tousled to one side. The former reality star, who channeled a boho chic look earlier this week for a modelling shoot, was clearly tying in with the Superman theme of the night.
Taking to Twiter, she explained: "Gone for a superhero-esque outfit haha #manofsteelpremiere." The film was clearly to her liking, as she later added: "Just at Man of Steel premiere--AMAZING!!! First gargantuan blockbuster of the year!!!"