Ben Affleck is starring as Batman in the new film and he'll be on the sofa alongside Henry Cavill who plays his Kryptonian opponent.
The ladies of the film will also be represented with Amy Adams, who portrays Lois Lane joining in the fun.
And as if all that isn't enough, music comes from Pet Shop Boys who'll be performing their new single, The Pop Kids.
The Graham Norton Show, BBC1, 10.25pm
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