The six housemates will all go head-to-head when phone lines open tonight (6 January) before one leaves the CBB house on Wednesday.
N-Dubz star Dappy and journalist Liz were first to be put up for eviction after Jim Davidson and Linda Nolan chose to free them from their handcuffs during Friday night's launch show.
Apprentice star Luisa, boxer Evander, glamour model Casey and Blue singer Lee found themselves up for the public vote following a task involving ropes and keys.
The foursome, along with Ollie Locke and Lionel Blair, were challenged to move a key along a knotted rope before unlocking their padlocks.
Ollie and Lionel were first to free themselves, meaning they instantly became immune to the public vote.
Celebrity Big Brother 2014: The lineup
Copyright: Channel 5