The fashionista joined a whole host of glamorous celebs as she posed up a storm on the pink carpet at the Earls Court Exhibition Centre in her androgynous ensemble.
Gorgeous Olivia always gets things just right on the fashion front and this time was certainly no different, with the starlet sporting a smart black tuxedo jacket, adding a skinny leather belt to help cinch in her waist.
The former City star also rocked a pair of eye-wateringly tight leather trousers while giving her getup a feminine touch with nude courts which were covered in black lace, featuring little ruffle details near the toes.
Olivia added a pop of colour with a green boxy clutch bag which stored all her evening essentials, finishing with berry red nails while ditching the statement jewellery, simply wearing her sparkling wedding ring on her finger.
Her caramel blonde tresses were mega-glossy and super-smooth and she amped up the smokiness with her make-up, circling her chocolate brown peepers with shimmery silver eyeshadow teamed with jet black kohl pencil.
Other attendees at the lavish event included One Direction's Liam Payne, who was joined by girlfriend Sophia Smith, and Chelsea gals Millie Mackintosh and Rosie Fortescue, who dressed up in racy sheer frocks for the occasion.
The Saturdays' Mollie King, Rochelle Humes and Vanessa White also took their places on the front row, while Ed Sheeran got the best view of the night by performing on stage alongside the stunning models... and he looked VERY happy to be there!
Check out the Victoria's Secret Fashion Show 2014 in pictures:
Copyright: WENN Lia Toby
What do you think of Olivia's outfit? Let us know by commenting below as the best comment across the site each week wins £50!
Reveal is now on Google Plus! Join us here for the latest pictures, fashion and celebrity news!
Got an iPad or iPhone? Reveal Mag is specially designed to fit!