The songstress wowed crowds as she joined country singers Little Big Town on stage before belting out her hit tune 'Bang Bang', and she certainly ensured she kept all eyes on her for the evening!
Dressing up for Bonfire Night, Ariana sported a see-through plastic crop top and matching layered skirt, with both featured bright white lights which glowed as she strutted her stuff on stage.
Is it wrong that we kind of want Ariana's festive outfit for ourselves? It's the PERFECT ensemble for New Year's Eve, don't cha think?!
The starlet amped up the glitz factor even more by lengthening her pins with towering heels covered in glitter, and also opted for a striking white manicure while sweeping her locks into her signature half-up, half-down hairdo.
Her skin was totally flawless and her eyes were decorated with warm shimmery coral eyeshadow and lashings of jet black mascara, and she dabbed a hint of highlighter on her cheeks before finishing with Hollywood red lipstick.
And it sounds like Ariana had a ball performing at the event, taking to Twitter to write: "Was an honour to perform on the #CMAs tn! Thanks so much @littlebigtown for welcoming me on your stage. The sweetest. Y'all sounded amazing."
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Watch Jessie J, Ariana Grande and Nicki Minaj's video for 'Bang Bang' below: