The model, DJ and wife of singer Brian looked stunning when she arrived at the launch of beauty clinic 43 Face in Notting Hill last night (17 April).
Vogue teamed a white and navy striped T-shirt with a black biker leather jacket, but it was her layered white skirt that really gave the look an extra edge.
Not only did the unusual mini-skirt go perfectly with her top, it also showed off her toned and tanned pins. Bravo, Vogue!
As well as matching black heels and clutch handbag, Vogue wore a cheeky on-trend orange lipstick.
Her blonde hair was glossy and loosely styled in waves.
Before arriving at the glitzy event, Vogue tweeted: "On my way to the launch @43_FACE I definitely need a champagne!! x"
Vogue and Brian married in September 2012 in a romantic ceremony at a medieval castle in Florence, Italy. The Irish couple met in a Letterkenny nightclub in May 2011.
Former Westlife star Brian was recently announced as the presenter of a brand new dating show called Stand By Your Man.
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