All eyes were on Kate Moss as she arrived – leaving everyone in no doubt that she is the Queen of Cool.
Wearing a cape studded with crystals, over a gorgeous vintage-inspired embellished top and grey skinnies tucked into the most amazing killer-heeled ankle boots, she shone.
Topshop have just announced announced that Kate Moss will be back designing a collection for them in 2014 – let's hope we'll be seeing a velvet cape in that range!
Up close she looked much younger than her 39 years, and there was no sign of the tum she displayed on holiday in Ibiza earlier this year.
Husband Jamie Hince arrived with her.
Georgia May Jagger had her make-up artist on hand in the VIP area which was cordoned off for the stars of the show.
She preened and happily posed for photographs with party guests.
The daughter of Rolling Stones front man, Mick Jagger, looked stunning in the tiniest butt-skimming embellished dress, reminiscent of 1970s Biba and designed by Julien Macdonald.
The designer was thrilled that young Georgia was rocking one of his creations and tweeted 'Wow!@GeorgiaMJaggeryou looked AMAZING in my dress at the @rimmellondonuk #Rimmel180 party last night!'
Her make-up artist created a fantastic look, with dark emerald metallic glam eyes, a rose-pink pout, and a mass of honey blonde crimped curls.
Georgia clearly loved being the centre of attention, and was happy to mingle with the crowd, enjoying the evening.
Delicous almond and vodka cocktails were served in jars with red and white straws, and there was a mini cooper emblazoned with Union Jack for revellers to pose against for intstagram pics.
Canapes included goat's cheese in Rimmel red macaroons, and mini ice cream cones containing lobster.
Guests were treated to a fashion show with models dressed in styles from every decade from Victorian times to the 20s, 50s, 60s, 70s and 80s.
To top it all, there was a live performance by Rita Ora, 22, looking London cool in a sharp Moschino tartan trouser suit with her signature Rimmel red pout.
'Hot Right Now' singer Rita is the latest face of Rimmel's 'Get The London Look' campaign.
Rita said, she'd "asked Rimmel if she could choose the names of the latest products." Apparently they said yes – so look out for Rita's words on the packaging!
Afterwards Rita tweeted "Love u ladies @georgiamjagger #KateMoss #Rimmel tonight was a blast!"
We couldn't agree more. Thank you Rimmel for a fantastic evening.