The Gossip Girl star took her place on the FROW next to Anna Wintour at the Gucci Spring Summer 2014 show at Milan Fashion Week on Wednesday (18 September).
Unsurprisingly she looked a million dollars, flaunting her figure in a skin-tight leather dress by Gucci. Mustard yellow isn't an easy colour to wear, so kudos to Blake for pulling it off!
Her head-turning frock featured a halterneck and belted waist, and she added metallic strappy heels.
She wore her sunkissed locks straight and applied bright red lippy for a dash of drama.
And we couldn't keep our eyes off her eye-popping wedding ring either. If we had a sparkler like that, we'd be flaunting it left, right and centre!
What do you think of Blake's outfit? Let us know by commenting below as the best comment across the site each week wins £50!